

Table of Electronic Configuration for the First 30 Elements
Understanding the Electronic Configuration Of First 30 Elements is essential in chemistry, as it reveals how electrons are arranged around the nucleus for elements from hydrogen through zinc. Mastering these configurations helps students predict properties, chemical reactivity, and trends across the periodic table in both Class 9 and Class 10 curricula. This article simplifies the rules, showcases succinct examples in shell and spdf forms, and highlights important exceptions and valency rules for the first 30 elements.
Basics of Electronic Configuration
The electronic configuration of an atom describes the distribution of electrons in different energy levels (K, L, M, N shells) and within sublevels (s, p, d, f orbitals). For the first 30 elements, these arrangements help explain atomic behavior, periodic patterns, and chemical bonding.
Key Rules to Write Electronic Configurations
- Aufbau Principle: Electrons occupy the lowest available energy orbitals first (1s → 2s → 2p → 3s → 3p → 4s → 3d...)
- Pauli Exclusion Principle: Each orbital holds a maximum of two electrons with opposite spins.
- Hund’s Rule: Every orbital in a subshell is singly filled before any is doubly filled.
Shells and Subshells
- K, L, M, N shells correspond to energy levels n = 1, 2, 3, 4
- Each shell contains subshells: s (2 electrons), p (6), d (10), f (14)
- For the first 30 elements, only s, p, and d subshells are filled
Electronic Configuration of the First 30 Elements (1–30)
Below is a quick reference for the electronic configuration of first 30 elements in spdf, both in shell and orbital notations, following the Aufbau principle:
- Hydrogen (H, 1): 1s1
- Helium (He, 2): 1s2
- Lithium (Li, 3): 1s2 2s1
- Beryllium (Be, 4): 1s2 2s2
- Boron (B, 5): 1s2 2s2 2p1
- Carbon (C, 6): 1s2 2s2 2p2
- Nitrogen (N, 7): 1s2 2s2 2p3
- Oxygen (O, 8): 1s2 2s2 2p4
- Fluorine (F, 9): 1s2 2s2 2p5
- Neon (Ne, 10): 1s2 2s2 2p6
- Sodium (Na, 11): 1s2 2s2 2p6 3s1
- Magnesium (Mg, 12): 1s2 2s2 2p6 3s2
- Aluminum (Al, 13): 1s2 2s2 2p6 3s2 3p1
- Silicon (Si, 14): 1s2 2s2 2p6 3s2 3p2
- Phosphorus (P, 15): 1s2 2s2 2p6 3s2 3p3
- Sulfur (S, 16): 1s2 2s2 2p6 3s2 3p4
- Chlorine (Cl, 17): 1s2 2s2 2p6 3s2 3p5
- Argon (Ar, 18): 1s2 2s2 2p6 3s2 3p6
- Potassium (K, 19): 1s2 2s2 2p6 3s2 3p6 4s1
- Calcium (Ca, 20): 1s2 2s2 2p6 3s2 3p6 4s2
- Scandium (Sc, 21): 1s2 2s2 2p6 3s2 3p6 3d1 4s2
- Titanium (Ti, 22): 1s2 2s2 2p6 3s2 3p6 3d2 4s2
- Vanadium (V, 23): 1s2 2s2 2p6 3s2 3p6 3d3 4s2
- Chromium (Cr, 24): 1s2 2s2 2p6 3s2 3p6 3d5 4s1 *
- Manganese (Mn, 25): 1s2 2s2 2p6 3s2 3p6 3d5 4s2
- Iron (Fe, 26): 1s2 2s2 2p6 3s2 3p6 3d6 4s2
- Cobalt (Co, 27): 1s2 2s2 2p6 3s2 3p6 3d7 4s2
- Nickel (Ni, 28): 1s2 2s2 2p6 3s2 3p6 3d8 4s2
- Copper (Cu, 29): 1s2 2s2 2p6 3s2 3p6 3d10 4s1 *
- Zinc (Zn, 30): 1s2 2s2 2p6 3s2 3p6 3d10 4s2
* Chromium and Copper are exceptions where half-filled or fully filled d-subshells increase stability.
Orbital Box Diagrams & Valency
The electronic configuration of first 30 elements with orbital diagram can be depicted using box diagrams, where arrows represent electrons. These diagrams visually emphasize principles like Hund’s Rule. Valency is determined by counting electrons in the outermost shell, which predicts chemical reactivity:
- Group 1 elements (Na, K) with 1 valence electron are highly reactive metals.
- Elements like Oxygen and Fluorine tend to gain electrons to achieve stability.
- Noble gases like Argon (Ar) possess complete shells, so their valency is zero.
Why Learning Electronic Configuration Matters
- Predicts chemical reactivity and bonding behavior.
- Explains periodic trends like atomic size and electronegativity.
- Helps classify elements based on their outer shell configurations.
Interested in how atomic models shaped electron configuration rules? Discover more about historical breakthroughs such as Bohr’s Model of Hydrogen Atom or the foundations of atomic physics right on Vedantu for deeper insights.
Quick Tips and Common Errors
- Do not mix up shell notation (K/L/M/N) with orbital notation (s/p/d/f).
- Always remember: 4s fills before 3d, but exceptions occur.
- Carefully count electrons to match the element’s atomic number.
To further strengthen your fundamental grasp of matter and atomic structure, you can also explore related topics like the basics of matter or test your skills using science MCQs for Class 9 on Vedantu.
In summary, understanding the Electronic Configuration Of First 30 Elements—whether in k l m n shells, as spdf notation, or using box diagrams—is a vital skill for any student of chemistry. This knowledge clarifies periodic trends, explains valency, and unlocks the prediction of reactivity and bonding patterns. Recognizing configuration exceptions like chromium and copper, and practicing step-by-step electron distribution, will help you excel in exams and deepen your appreciation for atomic theory.
FAQs on Electronic Configuration of the First 30 Elements Explained
1. What is the electronic configuration of the first 30 elements?
The electronic configuration of the first 30 elements shows how electrons are arranged in their atomic orbitals according to the Aufbau principle. Here is a table for quick reference:
- Hydrogen (H): 1s1
- Helium (He): 1s2
- Lithium (Li): 1s2 2s1
- Beryllium (Be): 1s2 2s2
- Boron (B): 1s2 2s2 2p1
- Carbon (C): 1s2 2s2 2p2
- Nitrogen (N): 1s2 2s2 2p3
- Oxygen (O): 1s2 2s2 2p4
- Fluorine (F): 1s2 2s2 2p5
- Neon (Ne): 1s2 2s2 2p6
- Sodium (Na): 1s2 2s2 2p6 3s1
- Magnesium (Mg): 1s2 2s2 2p6 3s2
- Aluminum (Al): 1s2 2s2 2p6 3s2 3p1
- Silicon (Si): 1s2 2s2 2p6 3s2 3p2
- Phosphorus (P): 1s2 2s2 2p6 3s2 3p3
- Sulfur (S): 1s2 2s2 2p6 3s2 3p4
- Chlorine (Cl): 1s2 2s2 2p6 3s2 3p5
- Argon (Ar): 1s2 2s2 2p6 3s2 3p6
- Potassium (K): 1s2 2s2 2p6 3s2 3p6 4s1
- Calcium (Ca): 1s2 2s2 2p6 3s2 3p6 4s2
- Scandium (Sc): 1s2 2s2 2p6 3s2 3p6 4s2 3d1
- Titanium (Ti): 1s2 2s2 2p6 3s2 3p6 4s2 3d2
- Vanadium (V): 1s2 2s2 2p6 3s2 3p6 4s2 3d3
- Chromium (Cr): 1s2 2s2 2p6 3s2 3p6 4s1 3d5
- Manganese (Mn): 1s2 2s2 2p6 3s2 3p6 4s2 3d5
- Iron (Fe): 1s2 2s2 2p6 3s2 3p6 4s2 3d6
- Cobalt (Co): 1s2 2s2 2p6 3s2 3p6 4s2 3d7
- Nickel (Ni): 1s2 2s2 2p6 3s2 3p6 4s2 3d8
- Copper (Cu): 1s2 2s2 2p6 3s2 3p6 4s1 3d10
- Zinc (Zn): 1s2 2s2 2p6 3s2 3p6 4s2 3d10
2. How do you write the electronic configuration for an element?
The electronic configuration for an element is written by filling up electrons into atomic orbitals based on their energy levels. The steps are:
- Start from the lowest energy orbital (1s) and follow the Aufbau principle.
- Use the order: 1s → 2s → 2p → 3s → 3p → 4s → 3d → 4p, etc.
- Fill each orbital according to its maximum capacity: s (2), p (6), d (10), f (14).
- Apply Hund's Rule and Pauli's Exclusion Principle for correct arrangements.
3. What exceptions should I remember in the electronic configurations up to element 30?
Some elements show exceptional electronic configurations due to extra stability of half-filled and fully-filled orbitals. Key exceptions include:
- Chromium (Cr, Z=24): [Ar] 4s1 3d5 instead of 4s2 3d4
- Copper (Cu, Z=29): [Ar] 4s1 3d10 instead of 4s2 3d9
4. Why is electronic configuration important in chemistry?
Electronic configuration determines element properties and chemical reactivity. It is important because:
- It explains an element’s position in the periodic table.
- It predicts valency and bonding behaviour.
- It helps understand periodic trends like atomic size and ionization energy.
5. How does electronic configuration affect the periodic table?
Electronic configuration shapes the periodic table's structure and is basis for grouping elements. Main effects:
- Elements in the same group have similar valence shell configurations and hence similar properties.
- Period number indicates number of energy shells.
- Block classification (s, p, d, f) derives from outermost electron configuration.
6. What is the electronic configuration of potassium and calcium?
Potassium and calcium are the 19th and 20th elements.
- Potassium (K): 1s2 2s2 2p6 3s2 3p6 4s1
- Calcium (Ca): 1s2 2s2 2p6 3s2 3p6 4s2
7. What is the electronic configuration of transition elements up to zinc?
Transition elements from Scandium (21) to Zinc (30) have electrons filling the 3d subshell after 4s:
- Scandium (Sc): [Ar] 4s2 3d1
- Titanium (Ti): [Ar] 4s2 3d2
- Vanadium (V): [Ar] 4s2 3d3
- Chromium (Cr): [Ar] 4s1 3d5 (exception)
- Manganese (Mn): [Ar] 4s2 3d5
- Iron (Fe): [Ar] 4s2 3d6
- Cobalt (Co): [Ar] 4s2 3d7
- Nickel (Ni): [Ar] 4s2 3d8
- Copper (Cu): [Ar] 4s1 3d10 (exception)
- Zinc (Zn): [Ar] 4s2 3d10
8. How do you use the Aufbau principle in writing electronic configurations?
The Aufbau principle states that electrons fill lower energy orbitals first. For writing configurations:
- Follow the order given by the n+l rule.
- Fill 1s first, then 2s, 2p, 3s, 3p, 4s, then 3d, etc.
- This helps ensure electrons are placed in the correct sequence as per the current exam guidelines.
9. What is the significance of valence electrons in the electronic configuration?
Valence electrons are the outermost electrons in an atom’s electronic configuration and determine chemical behaviour.
- They are involved in bond formation.
- They decide the valency of elements.
- Knowing valence electrons helps explain trends and predictions in the periodic table.
10. How does Hund’s Rule help in writing electronic configurations?
Hund’s Rule states that every orbital in a sublevel is singly filled before any is doubly filled. When writing electronic configurations:
- Place one electron in each orbital of a subshell before pairing.
- Ensures maximum multiplicity and correct structure for atoms like nitrogen (N).
11. State the electronic configuration of copper and name the rule violated in this configuration.
Copper (Cu, atomic number 29) has a unique electronic configuration: [Ar] 4s1 3d10. This configuration violates the expected order from the Aufbau principle, but occurs due to the extra stability of a fully-filled d-subshell.











